Bioinspired Catalysis


•  [FeII(TPA)(NCMe)2]2+ + H2O2. A model for cis-dihydroxylating Rieske dioxygenases

"Stereospecific Alkane Hydroxylation by Non-Heme Iron Catalysts: Mechanistic Evidence for an FeV=O Active Species," Chen, K. and Que, L., Jr., J. Am. Chem. Soc., 2001,123, 6327 -6337 (Article)

"Olefin cis-Dihydroxylation versus Epoxidation by Nonheme Iron Catalysts: Two Faces of an FeIII-OOH Coin," Chen, K.; Costas, M.; Kim, J.; Tipton, A. K.; Que, L., Jr., J. Am. Chem. Soc. 2002, 124, 3026-3035. (Article)

"Spin State Tuning of Non-Heme Iron-Catalyzed Hydrocarbon Oxidations: Participation of FeIII-OOH and FeV=O Intermediates," Chen, K.; Costas, M.; Que, L., Jr., J. Chem. Soc., Dalton Trans. 2002, 5, 672-679. (Article)







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